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General Description |
Liquid. Floats on water. |
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Reactivity Profile |
Dodecyl 2-methylacrylate is an ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Tends to polymerize. Oxidizing and reducing agents may initiate polymerization. Reaction may also occur when heated [USCG, 1999]. |
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Health Hazard |
Inhalation temporarily reduces blood pressure from 5 to 25%, increases respiratory rate, decreases heart rate, and causes some EKG changes. Liquid may cause irritation of eyes and skin. May be harmful if swallowed. |
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Fire Hazard |
Behavior in Fire: Heat can induce polymerization with rapid release of energy. Sealed containers may rupture explosively. |
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Flammability and Explosibility |
Nonflammable |
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Purification Methods |
Purify the ester by fractional distillation in a high vacuum. Add 0.05% of hydroquinone monomethyl ether as stabilizer. [Rehberg & Fischer Ind Eng Chem 40 1430 1948, Beilstein 2 III 1290, 2 IV 1528.] |
InChI:InChI=1/C16H30O2/c1-4-5-6-7-8-9-10-11-12-13-14-18-16(17)15(2)3/h2,4-14H2,1,3H3
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poly(methacrylic acid)
1-dodecyl alcohol
n-dodecyl methacrylate
| Conditions | Yield |
|---|---|
|
With
dicyclohexyl-carbodiimide;
In
dichloromethane;
at 20 ℃;
for 4h;
|
86% |
|
With
phosphoric acid; (p-tolueneslfonic acid, sulfosalicylic acid, resin KU-2x8); hydroquinone;
In
toluene;
Heating;
|
1-dodecyl alcohol
3-(2-methylpropenoyl)-oxazolidin-2-one
n-dodecyl methacrylate
| Conditions | Yield |
|---|---|
|
With
ytterbium(III) triflate;
In
acetonitrile;
at 90 ℃;
for 48h;
Sealed tube;
Inert atmosphere;
|
79% |
1-dodecyl alcohol
methacrylic acid methyl ester
poly(methacrylic acid)
3-(2-methylpropenoyl)-oxazolidin-2-one
dodecyl isobutyrate